An Improved Red Spectrum of the Methane or T-dwarf SDSS 1624+0029: Role of the Alkali Metals

A Keck~II low resolution spectrum shortward of ome-micron is presented for SDSS 1624+0029, the first field methane or T dwarf discovered in the Sloan Digital Sky Survey. Significant flux is detected down to the spectrum's short wavelength limit of 6200\AA. The spectrum exhibits a broad absorption feature centered at 7700\AA, which we interpret as the K~I 7665/7699 resonance doublet. The observed flux declines shortward of 7000\AA, due most likely to the red wing of the Na~I doublet. Both Cs~I doublet lines are detected more strongly than in an earlier red spectrum. Neither Li~I absorption nor H$\alpha$ emission are detected. An exploratory model fit to the spectrum suggests that the shape of the red spectrum can be primarily accounted for by the broad wings of the K~I and Na~I doublets. This behavior is consistent with the argument proffered by Burrows, Marley and Sharp that strong alkali absorption is principally responsible for depressing T dwarf spectra shortward of 1$\mu$m. In particular, there seems no compelling reason at this time to introduce dust or an additional opacity source in the atmosphere of the SDSS object. The width of the K~I and strengths of the Cs~I lines also indicate that the Sloan object is warmer than Gl~229B.Comment: accepted March 3, 2000 for Ap.J. Letters, LaTeX, 2 figure

A Flaring L5 Dwarf: The Nature of H\alpha Emission in Very Low Mass (Sub)Stellar Objects

Time series spectrophotometry of the L5 dwarf 2MASS 01443536-0716142 showed strong H\alpha emission which declined by nearly 75% in four consecutive exposures. The line was not detected in emission on a spectrum obtained eleven months later. This behavior constrasts with that of 2MASSI J1315309-264951, an L5 dwarf which has shown even stronger H\alpha emission on four separate occasions. The observational database suggests that L dwarfs can be found in such strong flares only occasionally, with a duty cycle of order 1%. In contrast, the few, continuously-strong H\alpha emitters, including PC 0025+0447 and 2MASSI J1237392+652615, must either be (1) objects no older than 10-100 Myrs with continuously-active accretion and/or chromospheres, but which apparently formed in isolation from known young stellar clusters and associations, or (2) objects empowered by a different and unknown mechanism for the H\alpha energy.Comment: 11 pages, 2 figures, Astronomical Journal in press -- Jan 2003 issu

SDSS J042348.57-041403.5AB: A Brown Dwarf Binary Straddling the L/T Transition

We present the discovery of SDSS J042348.57-041403.5 as a closely-separated (0"16) brown dwarf binary, resolved by the Hubble Space Telescope Near Infrared Camera and Multi-Object Spectrometer. Physical association is deduced from the angular proximity of the components and constraints on their common proper motion. SDSS0423-0414AB appears to be composed of two brown dwarfs with spectral types L6+/-1 and T2+/-1. Hence, this system straddles the transition between L dwarfs and T dwarfs, a unique evolutionary phase of brown dwarfs characterized by substantial shifts in spectral morphology over an apparently narrow effective temperature range. Binarity explains a number of unusual properties of SDSS 0423-0414, including its overluminosity and high effective temperature compared to other early-type T dwarfs, and possibly its conflicting spectral classifications (L7.5 in the optical, T0 in the near infrared). The relatively short estimated orbital period of this system (~15-20 yr) and the presence of Li I absorption in its combined light spectrum make it an ideal target for both resolved spectroscopy and dynamical mass measurements. SDSS 0423-0414AB joins a growing list of late-L/early-T dwarf binaries, the high percentage of which (~50%) may provide a natural explanation for observed peculiarities across the L/T transition.Comment: 6 pages, 2 figures, accepted for publication in Astrophysical Journal Letter

Characterization and gene expression analysis of the cir multi-gene family of plasmodium chabaudi chabaudi (AS)

Background: The pir genes comprise the largest multi-gene family in Plasmodium, with members found in P. vivax, P. knowlesi and the rodent malaria species. Despite comprising up to 5% of the genome, little is known about the functions of the proteins encoded by pir genes. P. chabaudi causes chronic infection in mice, which may be due to antigenic variation. In this model, pir genes are called cir s and may be involved in this mechanism, allowing evasion of host immune responses. In order to fully understand the role(s) of CIR proteins during P. chabaudi infection, a detailed characterization of the cir gene family was required. Results: The cir repertoire was annotated and a detailed bioinformatic characterization of the encoded CIR proteins was performed. Two major sub-families were identified, which have been named A and B. Members of each sub-family displayed different amino acid motifs, and were thus predicted to have undergone functional divergence. In addition, the expression of the entire cir repertoire was analyzed via RNA sequencing and microarray. Up to 40% of the cir gene repertoire was expressed in the parasite population during infection, and dominant cir transcripts could be identified. In addition, some differences were observed in the pattern of expression between the cir subgroups at the peak of P. chabaudi infection. Finally, specific cir genes were expressed at different time points during asexual blood stages. Conclusions: In conclusion, the large number of cir genes and their expression throughout the intraerythrocytic cycle of development indicates that CIR proteins are likely to be important for parasite survival. In particular, the detection of dominant cir transcripts at the peak of P. chabaudi infection supports the idea that CIR proteins are expressed, and could perform important functions in the biology of this parasite. Further application of the methodologies described here may allow the elucidation of CIR sub-family A and B protein functions, including their contribution to antigenic variation and immune evasion

Substellar Companions to Main Sequence Stars: No Brown Dwarf Desert at Wide Separations

We use three field L and T dwarfs which were discovered to be wide companions to known stars by the Two Micron All-Sky Survey (2MASS) to derive a preliminary brown dwarf companion frequency. Observed L and T dwarfs indicate that brown dwarfs are not unusually rare as wide (Delta >1000 A.U.) systems to F-M0 main-sequence stars (M>0.5M_sun, M_V<9.5), even though they are rare at close separation (Delta <3 A.U.), the ``brown dwarf desert.'' Stellar companions in these separation ranges are equally frequent, but brown dwarfs are >~ 10 times as frequent for wide than close separations. A brown dwarf wide-companion frequency as low as the 0.5% seen in the brown dwarf desert is ruled out by currently-available observations.Comment: ApJL, in pres

2MASS J05185995-2828372: Discovery of an Unresolved L/T Binary

We present the peculiar near-infrared spectrum of the newly discovered brown dwarf 2MASS J05185995-2828372, identified in the Two Micron All-Sky Survey. Features characteristic of both L and T dwarfs are present, namely strong carbon monoxide absorption in K-band, strong methane absorption in J- and H-bands, and red near-infrared colors. We consider several scenarios that could produce these features and conclude that the object is most likely to be an unresolved L/T binary system. We discuss how the estimated photometric properties of this object are consistent with the observed J-band brightening of brown dwarfs between late-L and early-T dwarfs, making detailed study of this system an important probe of the L/T transition.Comment: 4 pages, 4 figures (2 color), accepted to ApJ Letter

Hubble Space Telescope NICMOS Observations of T Dwarfs: Brown Dwarf Multiplicity and New Probes of the L/T Transition

We present the results of a Hubble Space Telescope NICMOS imaging survey of 22 T-type field brown dwarfs. Five are resolved as binary systems with angular separations of 0"05-0"35, and companionship is established on the basis of component F110W-F170M colors (indicative of CH4 absorption) and low probabilities of background contamination. Prior ground-based observations show 2MASS 1553+1532AB to be a common proper motion binary. The properties of these systems - low multiplicity fraction (11[+7][-3]% resolved, as corrected for sample selection baises), close projected separations (a = 1.8-5.0 AU) and near-unity mass ratios - are consistent with previous results for field brown dwarf binaries. Three of the binaries have components that span the poorly-understood transition between L dwarfs and T dwarfs. Spectral decomposition analysis of one of these, SDSS 1021-0304AB, reveals a peculiar flux reversal between its components, as its T5 secondary is ~30% brighter at 1.05 and 1.27 micron than its T1 primary. This system, 2MASS 0518-2828AB and SDSS 1534+1615AB all demonstrate that the J-band brightening observed between late-type L to mid-type T dwarfs is an intrinsic feature of this spectral transition, albeit less pronounced than previously surmised. We also find that the resolved binary fraction of L7 to T3.5 dwarfs is twice that of other L and T dwarfs, an anomaly that can be explained by a relatively rapid evolution of brown dwarfs through the L/T transition, perhaps driven by dynamic (nonequilibrium) depletion of photospheric condensates.Comment: ~40 pages, 17 figures, accepted for publication to ApJ. Note that emulateapj style file cuts off part of Table

Statistical thermodynamics unveils how ions influence an aqueous Diels-Alder reaction

The kinetics of Diels-Alder (DA) reactions in water has been known to be altered by salts for a long time. Yet the question how salts influence the reaction rate, either as rate-enhancing or rate-reducing additives, has so far remained unresolved. Conflicting hypotheses involve (i) indirect salt contributions through the modulation of internal pressure and (ii) making (or breaking) of the so-called “water-structure” by salts that strengthen (or weaken) the hydrophobic effect. In contrast to the qualitative nature of these hypotheses, here we answer this question quantitatively through a combination of transition state theory and fluctuation adsorption-solvation theory (FAST) using the DA reaction between anthracene-9-carbinol and N-ethylmaleimide as an example. We show that rate enhancement is driven by the salting out of the hydrophobic reagent, while rate-enhancing salts exhibit stronger affinity to the transition state